Much of the problem with DEX-COOL was GM's leak-prone V type engines. Their plastic intake manifolds, which also carried coolant to aid quick warmup, had a much lower rate of thermal expansion than the aluminum cylinder heads so leaks were almost inevitable anytime after 30,000 miles and up. Once air had a convenient path into the coolant, the results were predictable. Big Jim is right - the old green-snot-o'-death coolants with high silicate levels were susceptible to silicates falling out of suspension as a nasty glop. (Even unused in a sealed jug, this stuff only had a shelf life of 2-3 years. DEX-COOL, on the other hand, has a listed shelf life of eight years though its closer to indefinite.) Newer versions of conventional antifreeze have much better stability due to considerably reduced levels of silicates - with apparently no reduction in corrosion protection. But air in DEX-COOL leads to an entirely different gel chemistry - and the results ain't perty fer the engine. Keep air out of DEX-COOL, though, in a properly designed and functioning cooling system and the long term results are pristine. I also put over four years on a '96 Honda Accord with Havoline DEX-COOL without any regrets. Running DEX-COOL in a leak-prone cooling system is somewhat analagous to the poor slob who religiously downs a 325 mg aspirin tablet each day but packs in 3,000 calories of saturated fat, too - and then blames the aspirin for his eventual heart attack.
(On a side note, everything you pointed out about the dynamics of a non-pressurized puke tank is correct. My point, though, was that if the car owner maintains a proper level in the puke tank, and has a leak-free pressure cooling system and radiator filler neck to puke tank hose, once the air is purged, there won't be an avenue for air to re-enter the pressure system. My Sonata V6 is a case in point. I've just entered year three with WalMart's SuperTech dexclone. It was ovefilled initially, but intervening time-related water evaportion has brought the level in the puke tank down to only about an inch and a half above the midline when cold. I've checked the puke tank weekly and the cold fill level at the radiator monthly. Nothing has had to be added since I drained the slightly murky conventional swill Hyundai installed in Korea.)