ive had polyester resin refuse to cure atop epoxy, as well as having it cure, but refuse to bond.
both polyester and epoxy generate their own heat, and thinner applications take far longer to get tack free.
Generally the 'fiberglass resin' in parts store containers is a sanding resin vs laminating. it has a wax that rises to surface, encaPsulating the resin allowing it to ure tack free. This wax must be removed before any secondary bonding is attempted.
With cured Laminating resin, the hard but still tacky resin will accept another layer with no prep.
if the resin was worked with a brush after the wax rose and wax was effectively removed, then it will remain tacky forever after. you'll need to remove all the remaining wax, and brush on another layer and FFS, dont overwork it. Once it starts gelling, stop, walk away.
The sandpaper will clog up quickly when prepping for another layer.
Epoxy is a different animal.
West systems has great brand recognition, but is my least favorite to work with.