Higher ZDDP can lead to catalyst poisoning if a lot of it ends up in the exhaust system. While less is required with roller followers and roller lifters, this does not mean that other areas may not benefit from slightly higher concentrations.
Depends on the non-roller application here. An old broomstick cam'd SBF or SBC doesn't require a whole heck of a lot of ZDDP to keep the parts separated. A cam-over-bucket application doesn't either, generally, unless it's design is such that it produces high pressure on a small contact patch (VW PD engines for example).
Mobil 1 15W-50 was broadly spec'd for GM roller applications in Corvette and Camaro.
Ultimately, my view on it is that phosphorous levels, unconstrained, generally land at around 900-1,000ppm for ideal protection in most passenger car applications, as evidenced by the full-SAPS Euro oils. Even the C3 oils typically have phosphorous approaching the 900ppm limit.
Where we see considerably lower levels of phosphorous is in the API/ILSAC oils, which can be blended very inexpensively, and typically have a higher volatility ceiling. These are also lighter. You combine those things, and odds are much higher that the oil is going to end up in the exhaust system, so catalyst protection becomes a bigger focal point, so we see phosphorous not only more restricted by regulation, but we see less of it used.
I concur, that the ZDDP will only poison cats if the car is burning the oil, and the ZDDP is actually making it into the exhaust stream.
I was specifically talking about Mobil 1 5w50 Supercar designed for DLC finger followers in the Corvette Z06 not 15w50 Mobil 1. The finger follower as the name implies directly touches the cam. To help with wear resistance they oil was specifically forumulated with higher ZDDP, Viscocity, lower deteregents. It perfomed better in testing for cam / finger follower wear than Mobil 1 0w40 Euro, 5W40, 5w50 FS x2 et al.