Originally Posted By: StevieC
Originally Posted By: Craig in Canada
Due to chemistry, some typical automotive lead-acid cells will "never be the same" if they are allowed to discharge. This is particularly true if they are discharged for a while. This could be the basis of the warning.
I didn't know that... My mom discharged her battery a couple times when the car was new and then we recharged it and it seemed fine and lasted for 6 years before kicking the bucket.
Maybe that is why it didn't make it to 10 years like my other batteries.
It does depend on the exact chemistry an construction priorities used. Some chemistries can't withstand going dead - others are more tolerant. "Maintenance Free" and regular lead-acid batteries seem very similar at first glance other than one being "sealed", but they differ in chemistries for instance.
I'll see if I can dig up a link on the topic. I'm grasping at my memory but I think in some cases when the battery is in a discharged state some of the ions will precipitate out of the electrolyte into solids and fall to the bottom of the cells. Not only is this material no longer available for the galvanic reaction, but it can also form a bridge and short the plates.
From a really, really quick search:
http://www.batterystuff.com/tutorial_battery.html
Quote:
Basically there are two types of lead acid batteries (along with 3 sub categories); The two main types are Starting (cranking), and Deep Cycle (marine/golf cart). The starting battery (SLI starting lights ignition) is designed to deliver quick bursts of energy (such as starting engines) and therefore has a greater plate count. The plates are thinner and have somewhat different material composition. The deep cycle battery has less instant energy, but greater long-term energy delivery. Deep cycle batteries have thicker plates and can survive a number of discharge cycles. Starting batteries should not be used for deep cycle applications because the thinner plates are more prone to warping and pitting when discharged. The so-called Dual Purpose Battery is a compromise between the two types of batteries, though it is better to be more specific if possible.
So in a battery with particularly thin plates (I know my Interstate is lighter than other batteries for the same CCA rating - hmmm) they will warp and pit when in a discharged state.
That same link also covers sulphation which I brought up in another thread this week.