It will take quite some time to get the additive into the cooling system by going through the overflow tank. The best way to do it would be a coolant exchange with the additive incorporated into the replacement coolant.
This additive will not reduce the temperature of your engine - that's not what it's intended to do. If anything it should *increase* the coolant temperature. The coolant temperature will be kept relatively constant by the thermostat, so you will probably see no difference at all.
What it can do is reduce the metal temperature of the hottest parts of the motor internals that are in contact with the coolant by reducing the boiling effect. (probably in the head) Since water cools better than steam, at a point on the metal surface where bubbles form, the additive could reduce the point temperature. But at normal coolant pressure and flow rates, you would have to be driving pretty hard to reach that point anyway. Under normal driving conditions, and even spirited driving, this stuff will probably make no difference at all.
Raising the boiling point of the coolant is the job of the pressure cap anyway. Are you really driving this car so hard for so long that it would require such fluid modification? Instead of messing around with the coolant chemistry and possibly voiding the warranty, maybe you can use a radiator cap with a higher opening pressure or a lower temperature thermostat.