Top tier, as a marketing ploy is pretty poorly done. I don't see anyone going out of their way to find a Top Tier station, and if I was putting any effort into this at all, that would be my ultimate goal.
NOW, after writing my second reply in this thread, it occurred to me that there DOES exist inferior product in the supply chain. This process has to do with transmix. Transmix is the "in between" stuff that comes across in ALL of the pipelines that crisscross the United States, and probably every country in the world. Let's say a batch of 87 octane gas is scheduled to be pumped from storage tanks in Ohio, and it will be going to Pittsburgh PA. The pipeline will carry that batch just fine (let's make it 100,000 bbl) but it will be followed by a 50,000 bbl batch of diesel fuel, also going to Pittsburgh. The end of the first batch won't be completly in Pittsburgh before the "supplier" has to start PUSHING it with diesel fuel. Now you have to make a CUT to diesel in order to push the gas the rest of the way. This results in a short section of product "in between" that is neither the correct gravity for gasoline, and it is also NOT diesel fuel, it's mixed, that is called transmix.
What happens to that transmix when it arrives in Pittsburgh? You can't put it in the gas tank, and you can't sell it as diesel either....it goes into the transmix tank. A separate tank, not connected to the loading rack for sale to the public....sort of a degraded product unfit for sale. What happens to this stuff?
It gets re-refined!
Sometimes it goes back to the refinery and used as blend stock, SOMETIMES it goes to a special "little" refinery, where it is "flash refined" or basically the gas portion is boiled off and resold. What "should" be left is mostly low flash diesel.
This product, neither the gasoline portion, nor the diesel fuel portion would qualify as Top Tier product. But you can bet that it will be less expensive, and you can also bet there there is a chain of gas stations waiting to buy it.
At that point it can either be blended down, or sold as is. Blending it would mean just adding it to a big tank of good stuff so it would be mostly as good as new.
Sold as is probably would NOT meet top tier specs, whatever they are, since nobody is really spelling that out either.