That doesn’t feel quite right to me.
I don’t doubt the custom made part-these days pretty much anything on a steam loco is “custom made”.
With that said, on mainline American rail(and most of the world now for that matter) the locomotive’s brake shoes are pretty insignificant in the overall braking of the train. The brakes on each individual car are far more important.
For a prime example of this, see the story of the train that crashed through the floor of Washington, DC Union Station back in the 50s. Basically on the ~20 car train, someone in the yard had failed to open the air cock on the connection between the 4th and 5th car. The engineer noticed something was off when he applied a small amount of brake and it made no difference in speed. With the train at full emergency(I have it in the back of my head that PRR and most other railroads ran 110psi on passenger trains, not the normal 90psi of freight), which means no pressure in the brake line and as much available pressure on the brake shoes, the loco+four cars couldn’t bring the train to a stop before the end of the platform. Fortunately there were no serious injuries from that one. The locomotive, a GG-1 electric, was cut in pieces for removal, put back together in Altoona, and survives to this day in preservation.
Air compressor capacity can limit sustained braking and recovery on a big train, but the Big Boy was also built to haul 100 coal hoppers over the mountains. It has two big compressors right up front(they were making their presence known) so that wouldn’t be an issue. I doubt a single SD70ACE, what they had as part of this train, adds much compressor capacity.