We do a lot of AC work and if I had to throw a guess out there it would be that more than half we see are leaking at the schrader valves (charging ports) and the rest are bad compressors. We have done 6 compressors just this week. Then there's always the fun temp actuators up in the dash lol.
I always replace Schraders. I like putting a bit of nylock on the rubber seal and the threads. There is actually a tool to torque them.I was referring to the actual schrader valve itself - the part that seals the line under the cap. They have small o-rings but most caps have seals as well as a small back up