Originally Posted By: Cujet
Originally Posted By: JHZR2
Originally Posted By: i_hate_autofraud
For smoke alarms and other applications, alkaline is needed to get 1.5V per cell where NiMH or NICADs are only 1.2V, max 1.3V just after charging and they set off the low battery alarm way too soon.
+1.
For low power use, an alkaline will deliver around 2600mAh at 1.5V, as compared to 2000-2500mAh at 1.2V for NiMH.
Alkalines have higher impedance, so under high drain the actual voltage and capacity is lower.
Some NiMH have high self discharge. The low self discharge type is great.
They are ever so slightly larger than AAs. I had a toothbrush that woukdbt take rechargables because of that.
All true, but we must also consider that the proper measure of energy density is Watt/Hours. Top shelf alkaline batteries have a linear voltage drop as they are used, down to about 0.9 volts, at which point voltage drops rapidly. So capacity of a AA alkaline is typically said to be 1.225 volts on average, and an mAH capacity 2600, for a max energy of
3.9 watt hours.
NiMh batteries remain around 1.2 volts during the discharge cycle, and can have as much as 2850 mAH capacity. For
3.42 Watt/hour energy.
Close, but not quite there.
You neglect the discharge RATE in this equation. Vterminal=Vopencircuit-Current*impedance
Conduction voltage is huge in a practical circuit, and below some point, the electronics may not support operation.
Case in point, for a 500mA discharge:
I dont really care about how many Wh I get if its at a conduction voltage/condition that isnt relevant...