I'm doing the same thing and I use about 14.0V, but only because that was the lowest I could do with the adjustable switch mode power supply I have permanently installed in my trunk.
14.5V is better for fully charging the battery as that more closely resembles the alternator voltage, however I'd stick closer to 13.5 - 13.8V if the intent is to be able to leave it on long term.
Boiling the battery once in a while at 15.5V is one of the most potent things you can do for desulfation (better than using a desulfator IMO), but that's a different topic and I would not do that with the car electronics attached.
14.5V is better for fully charging the battery as that more closely resembles the alternator voltage, however I'd stick closer to 13.5 - 13.8V if the intent is to be able to leave it on long term.
Boiling the battery once in a while at 15.5V is one of the most potent things you can do for desulfation (better than using a desulfator IMO), but that's a different topic and I would not do that with the car electronics attached.