I'd imagine Jay is referring to dry film lubes for products that work well. If you can pour or rub dirt and or sand on a chain and it sticks to the chain, then you may want to try a different chain care product, especially if your chain driven product is exposed to contaminants (i.e. off road motorcycles).
Oil’s can provide good film strength as long as the oil is there, but the oil film is quickly displaced or washed off or runs off unless it’s replenished and it should be obvious to all of us that oils attract dirt. The Scott oilier that some people use on street bikes keeps chains continuously lubed and it’s probably a good option for street bikes, but if the chain is going to be frequently exposed to contaminants such as dirt, sand, mud, etc, then oil by itself is probably not the best choice for a chain lube.
Waxes have come a long ways, but there are still many chain wax products that attract dirt, sand, dust, etc. Most of the chain waxes I’ve seen form a coating on the outside of the chain and they don’t do much in the way of penetrating into the links. Many don’t hold up well in water, especially if you’re riding an off road bike through water crossings, bogs, etc. Many waxes also have a tendency to build up and form a cake of gritty goop on the chain, especially inside the countershaft cavity. The wax itself doesn’t provide much protection in the way of shock, load or film strength and many of them cake up to form a grinding compound if they become contaminated. While some chain wax products are better than others, I feel there are better choices.
WD40 always brings out strong opinions on both sides of the fence and for good reason, but I’m sure the more informed group here would agree that WD40 itself isn’t the best lubricant or corrosion protector and doesn’t offer much in the way of film strength to minimize shock & load, etc. It is however a very good water displacer (hence the name WD). Its solvency also cleans things pretty well and since we all know a clean chain is a happy chain, then it should makes since that WD40 can be good for a chain in the sense it disperses / washes away abrasives and other contaminants that would otherwise shorten chain life in addition to providing very limited lubrication and temporary corrosion protection.
Some people say WD40 does not affect o-rings and some disagree, but there’s good reason for this because not all rings are made from the same materials, process or share the same qualities. Many of the higher performance name brand chains today use high quality materials for their rings and WD40 will likely ‘not’ pose any issues during the ‘normal’ life of a motorcycle chain, but there are chains out there that use lower quality materials or sub standard processes for their rings and they can be subject to deterioration from the use of WD40. I think WD40 has its place and can be used with good results on many chains, but we should all be smart enough to know that it’s far from being the best product at providing protection in the way of film strength, shock, load, corrosion, etc.
Dry film lubes such as Schaeffer’s 227 Moly Roller Chain Lube have a number of advantages. First of all, they don’t attract or hold dirt, dust, sand or other contaminants and that in itself is a huge plus compared to wet, sticky or gooey lubes. They also typically resist water washout much better than other types of chain lubes and some have stronger attractions to metal surfaces than many of the oils or wax products. There are many good choices out there, but I’ve been using Schaeffer’s 227 Moly Roller Chain lube with excellent results for off road race bikes. I also like the way the chain / sprockets look after this product is used and they stay looking great for a long time. There is usually a significant & noticeable reduction in friction & noise with the use of this product that you can feel for yourself if you spin your rear wheel by hand while your bike is on a stand. Lube your clean chain with WD40 and spin your rear wheel. Then dry it off and lube it with Schaeffer’s 227 and you’ll hear and feel the difference.
http://www.schaefferoil.com/datapdf/227.pdf
The Schaeffer’s product contains a super thin carrier that disperses microscopic platelets of dry lubrication (MoS2 / Molybdenum Disulfide) that are ‘attracted’ to metal surfaces. These microscopic platelets fill the microscopic pores in the metal and form a sacrificial overlapping friction reducing protective armor coating that’s very resistant to water washout and corrosion. Here’s some interesting links on this site about Moly in general…
http://www.bobistheoilguy.com/moly.html
http://www.bobistheoilguy.com/moly1.html
http://www.bobistheoilguy.com/moly2.html
http://www.bobistheoilguy.com/moly3.html
http://www.bobistheoilguy.com/moly4.html
The Schaeffer’s moly roller chain lube product is not a product that’s used just a few seconds before you go riding. It goes on very wet and is very runny so it can penetrate into the links, but the carrier will dry out within several hours and will leave your chain dry to the touch by the next day, so keep that in mind when using this product or something similar to it.
Another very interesting dry film chain lube product is Ultra Film. ‘Jaybird’ hasn’t mentioned it, but I believe the following link is a link to his company and the products he sells / believes in. I believe he just runs this company on the side as a hobby because he has a passion for chains and likes ‘helping’ others, but I think he works full time in an industry that has to do with manufacturing lubricants, chain lubricators, conveyor components and other chain driven industrial equipment based on what I’ve surmised from reading information in various threads.
I personally tried out some of the Ultra Film product a ways back and it worked very well, but I still have a lot of the Schaeffers 227 on hand and I may as well use it up and then I’ll evaluate my choices again at that time, but I do know they’re both good products. Here’s a link to what I think is Jaybird’s web site that has various product and technical info on it…
http://www.best-motorcycle-chain-lube.com
If you like reading about chains / sprockets, then take a look a some of his tech articles…
http://www.best-motorcycle-chain-lube.com/motorcycle_maintenance_chain_sprocket_tips.htm
In summary, I think people who take good care of their chains will get decent life from their chains / sprockets, particularly if the chain / sprockets are kept clean, adjusted and aligned, no matter what their lube choice is as long as they’re applying their lube with some frequency. I also believe that using a high quality dry film lube will significantly extend the life of chains / sprockets compared to using chain oils, chain waxes, WD40, etc, especially if the chain is used in a harsh environment (i.e. off road use).