Understanding grease, incl. compatibility, application, chemistry, and history (deciphering the zillion lubricants)

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Oct 3, 2025
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Yeesh;
I feel a little bad - first post and I'm diving in to make a big one.
I've somehow always ended up here through web searches but never took the step to join and post.

Introduction
I have more grease-type lubricants than just about any other type of chemical, with adhesives maybe coming in close.
Off the top of my head I have: Molybdenum grease, Lithium grease, Mobil 1 synthetic grease, General Purpose grease (from the 90s lol), Silicone grease, food safe silicone grease, Waterproof grease, Mercedes high temperature bearing grease, animal tallow, vaseline, dielectric grease, paraffin wax (is a grease?)... there are more but I literally don't even know what they are.

Adding non-machinery (i.e. engine oil) lubricants to that equation: WD40 (yes? no?), graphite, ballistol, silicone spray, kroil, air tool oil, liquid wrench super lube, tap oil, and more that I can't remember.

Each of these I've acquired for particular jobs that I've done that have called for it, but my frustration: I genuinely do not know what to apply how when or where, except for general ideas. I do not know what is compatible with: various metals, various plastics, wood, rubber, etc. Ballistol is great b/c it's compatible with all the above (except brass and zinc!). The frustration manifests when you find yourself buying hyper-specific lubricants, i.e. garage door lube which is just absurd IMO.

History
So I don't mean agonizing over what the romans used, but rather understanding what greases emerged when.
Rendered animal fat was used in conjunction with wooden bearings/bushings (I think Lignum Vitae is used)

It's my understanding sodium was first used, then potassium, and finally lithium became a sort of standard. In between there came synthetic greases... whatever that means. Silicone is relatively new on the scene, and PTFE (teflon)-powder infused greases came in the 90s?

This helps when working on vehicles and deciding what grease should go where. An older car will be fine with dinosaur oil, b/c synthetic oils didn't exist yet. Same principle with greases; even new cars with "old" technologies can obviosuly accept certain greases.

Chemistry
I think grease is just soap mixed with mineral oil (or vegetable oil)?
https://en.wikipedia.org/wiki/Grease_(lubricant)?useskin=vector

Where mineral oils are simply long-chain alkanes... I think many things we call greases are not actually greases. This is very common when chemistry translates into the "real world". Silicones are long-chain siloxanes.... what makes them "greases"? What's the difference between silicone lube and silicone adhesive/caulk? Wikipedia says "Typically, a dry-set lubricant is delivered with a solvent carrier to penetrate the mechanism. The solvent then evaporates, leaving a clear film that lubricates", so the "greases" are more like silicone infused greases.

What is "synthetic grease" and how does that differ from regular grease? What's "dielectric grease"... and on that note, what is even a "dielectric"?
What differences are there between "cheap" greases and more expensive products like amsoil or Mercedes High Temperature Bearing Grease that my mechanic swears by.

Can lithium greases act as an antidepressant for machinists down on their luck?

All of this then goes to:

Application:
This is really what I want to know. What greases go where. Why are certain greases used for certain applications. What's in "garage door lube". Why does BMW specify moly-grease for the driveshaft splines on their bikes?

I've heard people claim silicone lube is silicone lube... ??? Is this true? Which greases are edible, or "food grade", and which are not? What is "waterproof grease" that Danco sells, and how is it different from my red mobil 1 synthetic grease?
If you have old japanese electronics that came with some white grease on the plastic gears, what grease is that??

I did some research prior to posting here, and there are actually grease guide posters, with tables dictating what goes where. I saw these in two flavors: 1. indecipherable industry letters, 2. manufacturers' individual products with their applications.
Why don't they use moly greases in wheel bearings? Or silicone greases? Which are interchangeable, and which cocktails are used for which specific applications?

Compatibility:
What greases work with what? I know vaseline will destroy wood (found this out the hardway), but parraffin wax will not.
What greases can/should be applied to rubber, and which should not? What works on plastic? Why or why not? Silicones are horrible to clean up... but why don't we just use silicones everywhere? What greases work with what metals? Are there metal incompatibilities?

These are the questions I'd like to have answers on.... ideally I'd have a big huge poster in my garage where I can reference what goes where.... and I've found a few, but idk. None of them really fulfill my wishes... either indecipherable industry classifications, or a blatant ad. Then again I haven't looked extensively either.
 
Some background Info:


 
Some background Info:


This is gold.

Buy a copy of the NLGI Lubricating Grease Guide, Seventh Edition. It will all of your questions
That's a great tip; it's unfortunately out of my budget, b/c I already spent it all on grease.
 
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I have a major contribution to help with these questions: “dielectric” means insulating on non-conductive. Superb post from a BITOG greenhorn.
 
This is gold.


That's a great tip; it's unfortunately out of my budget, b/c I already spent it all on grease.
The greases in all segments are about 84% soap including aluminum, calcium and lithium variants. These are further categorized by dropping points above or below 180°C which approximately aligns with simple vs. complex. The soaps are formed through reactions between fatty and other acids and a metal source. For example, the aluminum complex molecule is the product between a fatty acid, a complexing acid (usually benzoic) and an aluminum source. These are all solubilized in oil and blended at about 210-220°F for about an hour. Then the solution is cooked which is heating to about 400°F and then cooled. Additives are added and the mixture is milled/homogenized.

Complexing raises dropping point. For example, lithium 12 hydroxystearate (simple Li) has a dropping point of about 370-380°F. Lithium complexes have dropping points typically over 500°F. Dropping point is an important consideration when determining the upper service limit of the grease.
 
Most general consumption greases are soap based, but there are also clay based greases available, and the two don't mix. Gotta pay attention if the application is specific.
 
The greases in all segments are about 84% soap including aluminum, calcium and lithium variants. These are further categorized by dropping points above or below 180°C which approximately aligns with simple vs. complex. The soaps are formed through reactions between fatty and other acids and a metal source. For example, the aluminum complex molecule is the product between a fatty acid, a complexing acid (usually benzoic) and an aluminum source. These are all solubilized in oil and blended at about 210-220°F for about an hour. Then the solution is cooked which is heating to about 400°F and then cooled. Additives are added and the mixture is milled/homogenized.

Complexing raises dropping point. For example, lithium 12 hydroxystearate (simple Li) has a dropping point of about 370-380°F. Lithium complexes have dropping points typically over 500°F. Dropping point is an important consideration when determining the upper service limit of the grease.
Think you got your % flipped grease is typically around 80-85% oil and then 15-20% thickener.

Remember the oil still does the lubricating!
 
Think you got your % flipped grease is typically around 80-85% oil and then 15-20% thickener.

Remember the oil still does the lubricating!
Nothing was flipped, you missed the point of what I was saying. The topic was referred to business sectors and not formulas in response to the OP's statement "So greases are soaps mixed with oil?" I was not saying that grease is comprised of 84% soap. I was saying that 84% of greases manufactured are soap thickened: 4% aluminum variants, 23% calcium variants and 57% lithium variants. These numbers are from the NLGI 2024 Grease Production Survey.

The 16% balance is comprised of non-reactive gellants like silica, carbon black, PTFE or clay and reactive gels such as calcium sulfonate and polyurea
 
Nothing was flipped, you missed the point of what I was saying. The topic was referred to business sectors and not formulas in response to the OP's statement "So greases are soaps mixed with oil?" I was not saying that grease is comprised of 84% soap. I was saying that 84% of greases manufactured are soap thickened: 4% aluminum variants, 23% calcium variants and 57% lithium variants. These numbers are from the NLGI 2024 Grease Production Survey.

The 16% balance is comprised of non-reactive gellants like silica, carbon black, PTFE or clay and reactive gels such as calcium sulfonate and polyurea
Ahh yep re-reading I can see what you were going for.

Thanks!
 
Some background Info:


I went through both sentence by sentence; this is genuinely the information I came here for. I was hoping for a part 3, 4, and 5.

So now I have more questions.

This part left me confused:
Since Metallic Soap Thickeners are rarely used, we will concentrate on the Complex metallic soaps and other thickeners.

Complex Metallic Soap Thickeners gives the grease a higher temperature boost with better oxidation and high drop points. We will discuss advantages and disadvantages of each grease below.

What is meant here by "complex"? I took it to mean a cocktail of metallic thickeners, but re-reading, that doesn't seem to be the case.
I guess it means a Coordination Complex?
Then how is this different from a "single metallic soap"?

"EP" was mentioned a number of times, i.e.:
Lithium Complex – Lithium greases, especially the EP fortified greases
What is EP?

There no mention of silicone grease... is silicone simply not a grease at all? I guess butter or other thick fats wouldn't be considered greases? Prior to posting I thought grease was the heaviest byproduct of oil refining/cracking.

Finally, and more generally: doesn't water dissolve soap? So where does the water resistance come from?

When I get the chance I'm going to look more closely at the various greases I have laying around, including the special mercedes bearing grease. Hopefully I can build some intuition for what is what, and what goes where... and also what greases are worth keeping on hand and where to apply them. Information like this is becoming increasingly hard to find in this brave new world.
 
I went through both sentence by sentence; this is genuinely the information I came here for. I was hoping for a part 3, 4, and 5.

So now I have more questions.

This part left me confused:


What is meant here by "complex"? I took it to mean a cocktail of metallic thickeners, but re-reading, that doesn't seem to be the case.
I guess it means a Coordination Complex?
Then how is this different from a "single metallic soap"?
Here is a good article from the STLE:

https://www.stle.org/images/pdf/STLE_ORG/BOK/LS/Grease/Grease Chemistry Thickner.pdf
"EP" was mentioned a number of times, i.e.:

What is EP?
Extreme Pressure. An additive chemistry.
There no mention of silicone grease... is silicone simply not a grease at all? I guess butter or other thick fats wouldn't be considered greases? Prior to posting I thought grease was the heaviest byproduct of oil refining/cracking.
No, grease is a formulated, semi-solid lubricant. Asphalt is one of the heaviest byproducts of petroleum refining.

Silicone grease is a translucent, viscous lubricant made from a combination of silicone oil and a thickening agent.

Finally, and more generally: doesn't water dissolve soap? So where does the water resistance come from?
An additive provides water resistance.

Many additive chemistries are mixed with a base oil to provide various functions.
 
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Here’s a good primer on the differences between a lithium grease vs lithium complex grease:

https://www.mystiklubes.com/Articles/Grease/LithiumVsLithumComplexGrease.jsp

Non-complexed or “simple” greases typically have lower operating temperature limitations. For a lithium grease the “soap” is a salt formed by lithium and a fatty acid often 12- hydroxystearate.

There is a heck of a lot of nuance and information to learn about grease. Another approach that might be worthwhile is looking at the applications you’re servicing and seeking feedback on what products might serve you well in them. You can then use what you’re learning here to understand if the recommendations you get make sense or not.
 
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