The lack of ethanol in the fuel certainly is beneficial. However the higher octane most likely is not, and in some cases may be slightly detrimental to power.
The ONLY ethanol free gas available here is 91-94 octane premium. I would pay an extra cent or two per liter for 87 octane, ethanol free gas any day but it is not available. Buying premium 91 can be as much as 10-12 cents more per liter and that is just not going to come close to paying for itself in fuel economy, and the miniscule power gain that might be there certainly isn't worth the price.
I do buy it(Shell V-Power 91oct) for my OPE as it is older and ethanol is particularly damaging to the fuel lines etc in Briggs motors. Sometimes when I fill the gas can for the OPE with the V Power I will fill the truck with it as well and dump some Redline fuel system cleaner in for a good cleaning.
Other than that, it's Petro Canada 87 octane, as I have their points card, all brands are priced the same and all the family vehicles run just fine on it.