Esters Vs. PAO

Status
Not open for further replies.
Originally Posted By: Jeffs2006EvoIX
Is there any seal swell diferences in the use of an ester based oil vs a PAO or are the additives for seals the same throughout the spectrum of oils?


Yes, esters provide much more seal swell which is why most ester oils contain some PAO.

You might want to do a search for Tom NJ's posts on the subject, there is a lot of info there.
 
Originally Posted By: vxcalais


I always thought PAO had poor solvency and mixing and was very poor at cleaning on its own, which is why it needs the extra added cleansing additives adding to TBN. Group 3 is the same. Esters have a natural cleaning characteristic, same as Group 1 and 2, but contaminants can form out of Group 1 oils as they are not as refined etc. Correct me if i am wrong anyone. This is only how i have understood it all this time.


This is a gross oversimplification. TomNJ has also addressed this excellently in other threads. Yes, some PAO's aren't as polar as some esters. But to imply they have trouble "mixing" or somehow they need extra TBN boosting additives is incorrect.
 
Originally Posted By: Ben99GT
Tom NJ needs to chime in on this thread.

Obviously I'm no expert, Tom is, but I would think that POE's polar nature and natural lubricity would really shine in rear differentials. That's precisely why I run RL gear oils. Even when I finally move away from $9/qt ester motor oils in the F150, I will definitely stick with ester-based gear oils.


Data I have seen show Poly Glycols are best for bevel gear sets. One benefit is they can run cooler that mineral or PAO lubes, all else being "equal" which is not really possbile. PAOs are highly polar so they do real good in high contact pressure, sliding teeth applications like hypoid gear sets. Risky to use in auto applications due to incompatibilities PAG can have with mineral oils. PAGs are used in very high end industrial gearbox lubes. Its easier to control oil mixing in a factory than say in a fleet of vehicles.
 
You said: PAOs are highly polar .

Not one of the attributes of PAO from what I recall. POE's are very polar. I think you got those switched around.
 
Originally Posted By: AzFireGuy79
You said: PAOs are highly polar .

Not one of the attributes of PAO from what I recall. POE's are very polar. I think you got those switched around.


Yea, I think he meant POE or PAG as they are both highly polar by nature, PAO has very low polarity.
 
Originally Posted By: Jeffs2006EvoIX



The Idleing down part really isn't necessary any longer since most turbos of the day are water and oil cooled, so the temp of the turbo stays consistant. Its not like the old days when a turbo was pushed you can actually see it glow red.


I gotta disargee here...there's nothing new under the sun about combination water and oil-cooled turbo bearings, and the temp of the turbo DOES NOT "stay consistent." When you demand boost, the turbine wheels get hot. Demand it long enough, and they'll still glow red. Even running the turbo "moderately," the turbine wheel gets up to exhaust-gas temperature. If you just shut it down, the water stops flowing through the turbo cooling jacket (if present) and the oil stops flowing through the bearing. The wheel is sitting there nearly red-hot, and that heat will migrate from the wheel, down the shaft, into the bearing and housing, and will subject the oil remaining in the bearing to extreme high temperatures. That doesn't matter if its your EVO turbo, the Garrett on a 1988 Chrysler Turbo II, or the Holset on a Cummins N-14 in a Kenworth (actually diesel turbos cool even quicker at idle since diesels have a very cool and high-flow exhaust stream at idle compared to gasoline engines).

The idea is to get the EXHAUST GAS temp down low and keep it that way for a couple of minutes before shut down, that way the exhaust stream (even though it may be 500 degrees F) will cool down the 1100 degree F turbine wheel, rather than letting all that heat migrate down into the bearing housing. The way to get the absolute coolest EGT is to idle the engine with no load, which is why some turbo cars (RX-8, for one IIRC) have an idle cool-down system built into the engine controller. You can turn the key off, lock the car, and walk away and it will idle until the engine controller thinks the turbine is sufficiently cool.
 
Originally Posted By: Ben99GT
I honestly can't of anything group III would bring to the table in a PAO/POE mix other than lower costs.


Hmmm. Possibly. But I thought (and may be wrong here) that certain anti-wear additives were significantly more soluble in Group III than in esters. I *know* that Group III can carry additives better than PAO, so if there is only a small percentage of esters in the blend then Group III is even more beneficial.
 
Originally Posted By: 440Magnum
Originally Posted By: Ben99GT
I honestly can't of anything group III would bring to the table in a PAO/POE mix other than lower costs.


Hmmm. Possibly. But I thought (and may be wrong here) that certain anti-wear additives were significantly more soluble in Group III than in esters. I *know* that Group III can carry additives better than PAO, so if there is only a small percentage of esters in the blend then Group III is even more beneficial.


Everything I've read on the subject says POE is far more soluble than group I-III, group III being the worst of the three in this regard.
 
Originally Posted By: 440Magnum
The way to get the absolute coolest EGT is to idle the engine with no load, which is why some turbo cars (RX-8, for one IIRC) have an idle cool-down system built into the engine controller. You can turn the key off, lock the car, and walk away and it will idle until the engine controller thinks the turbine is sufficiently cool.

The RX-8 is naturally aspirated. Were you thinking of the RX-7?

In any case, you just described the operation of a "turbo timer," which apparently is a fairly easy modification to install on many cars.
 
Originally Posted By: AzFireGuy79
You said: PAOs are highly polar .

Not one of the attributes of PAO from what I recall. POE's are very polar. I think you got those switched around.


No, I meant to say Poly Glycol (PAG) are highly polar.
 
Originally Posted By: 440Magnum
Originally Posted By: Jeffs2006EvoIX



The Idleing down part really isn't necessary any longer since most turbos of the day are water and oil cooled, so the temp of the turbo stays consistant. Its not like the old days when a turbo was pushed you can actually see it glow red.


I gotta disargee here...there's nothing new under the sun about combination water and oil-cooled turbo bearings, and the temp of the turbo DOES NOT "stay consistent." When you demand boost, the turbine wheels get hot. Demand it long enough, and they'll still glow red. Even running the turbo "moderately," the turbine wheel gets up to exhaust-gas temperature. If you just shut it down, the water stops flowing through the turbo cooling jacket (if present) and the oil stops flowing through the bearing. The wheel is sitting there nearly red-hot, and that heat will migrate from the wheel, down the shaft, into the bearing and housing, and will subject the oil remaining in the bearing to extreme high temperatures. That doesn't matter if its your EVO turbo, the Garrett on a 1988 Chrysler Turbo II, or the Holset on a Cummins N-14 in a Kenworth (actually diesel turbos cool even quicker at idle since diesels have a very cool and high-flow exhaust stream at idle compared to gasoline engines).

The idea is to get the EXHAUST GAS temp down low and keep it that way for a couple of minutes before shut down, that way the exhaust stream (even though it may be 500 degrees F) will cool down the 1100 degree F turbine wheel, rather than letting all that heat migrate down into the bearing housing. The way to get the absolute coolest EGT is to idle the engine with no load, which is why some turbo cars (RX-8, for one IIRC) have an idle cool-down system built into the engine controller. You can turn the key off, lock the car, and walk away and it will idle until the engine controller thinks the turbine is sufficiently cool.


All I know is this. The Turbo is Water Cooled and Oil cooled. 3 Hrs on the dyno at WOT 90% of that time, the turbo housing never got over 300F by thermo temp. Which is well within the ability of most synthetics. I never saw my turbo glow red, and my tuner who builds Evo race engines does not idle the car down after the dyno runs. When asked why? He said the turbo is water cooled and never gets hot enough watch. He did a thermo check and the Temp was always under 300F. This is one reason why Mits wanted a synthetic in this car. Anywayz, I can talk Evo and Trubo's all day long. That I do know something about. haha. Non water cooled turbo, your right. Water cooled?? I will agree to dissagree with you just from my personal experience on and off the race track and dyno on my own car.
 
Everyone has their own driving style, and each car has its own design. All I can say about my car, the Evo, is it was built to be driven hard. Comes from the factory boasted more power per liter than any other production motor at its time of production (2005) It comes with forged components, natrium filled valves and even hollow cam shafts to save rotational mass. HUGE factory oil cooler, and a turbo that can put out over 100whp more than stock and still be reliable. Mobil 1 was factory fill. But as the motor gets pushed more and more past its OEM specs, I just feel that the oil needs to be upgraded too. Is why I am here to obtain the knowledge to choose wisely, not to debate or argue over petty controversal issues. Not to mock this site, but its no different than any other site that I have seen thus far, for people starting pety arguments. Anaywayz, for the folks responding, and giving good info, I really appreciate it. This site has allot of knowledge and its allot to soak in. That is for sure...
 
Last edited:
If you feel as though mobil 1 isnt up to the task look at something like Motul or Redline. I really dont think its needed though. But if it makes you feel more confident than thats what counts. M1 0w-40 is used in plenty of race motors putting out many more hp than your EVO and under much more stress than you could ever hope to dish out on the street or track.

Now if you were running a 1000hp turbocharged v-8 or a 600hp turbo 4 banger, then of course an expensive ester oil would be an easy choice. I just dont see a need. I happen to have a 1000rwhp ERL LS2 powered SS camaro and I use RL 5w30 or 10w-40. I cant prove I need it, but im not taking any chances. If this is how you are thinking nobody can ever fault you. They may just view it as overkill.
 
Last edited:
Originally Posted By: Jeffs2006EvoIX
Originally Posted By: 440Magnum
Originally Posted By: Jeffs2006EvoIX



The Idleing down part really isn't necessary any longer since most turbos of the day are water and oil cooled, so the temp of the turbo stays consistant. Its not like the old days when a turbo was pushed you can actually see it glow red.


I gotta disargee here...there's nothing new under the sun about combination water and oil-cooled turbo bearings, and the temp of the turbo DOES NOT "stay consistent." When you demand boost, the turbine wheels get hot. Demand it long enough, and they'll still glow red. Even running the turbo "moderately," the turbine wheel gets up to exhaust-gas temperature. If you just shut it down, the water stops flowing through the turbo cooling jacket (if present) and the oil stops flowing through the bearing. The wheel is sitting there nearly red-hot, and that heat will migrate from the wheel, down the shaft, into the bearing and housing, and will subject the oil remaining in the bearing to extreme high temperatures. That doesn't matter if its your EVO turbo, the Garrett on a 1988 Chrysler Turbo II, or the Holset on a Cummins N-14 in a Kenworth (actually diesel turbos cool even quicker at idle since diesels have a very cool and high-flow exhaust stream at idle compared to gasoline engines).

The idea is to get the EXHAUST GAS temp down low and keep it that way for a couple of minutes before shut down, that way the exhaust stream (even though it may be 500 degrees F) will cool down the 1100 degree F turbine wheel, rather than letting all that heat migrate down into the bearing housing. The way to get the absolute coolest EGT is to idle the engine with no load, which is why some turbo cars (RX-8, for one IIRC) have an idle cool-down system built into the engine controller. You can turn the key off, lock the car, and walk away and it will idle until the engine controller thinks the turbine is sufficiently cool.


All I know is this. The Turbo is Water Cooled and Oil cooled. 3 Hrs on the dyno at WOT 90% of that time, the turbo housing never got over 300F by thermo temp. Which is well within the ability of most synthetics. I never saw my turbo glow red, and my tuner who builds Evo race engines does not idle the car down after the dyno runs. When asked why? He said the turbo is water cooled and never gets hot enough watch.


The water DOES NOT continue circulate strongly (maybe not at all depending on turbo placement relative to the rest of the cooling system) after shutdown. The turbine wheel itself, not the housing, is what gets thermally soaked up to the full EGT, and subsequently conducts heat to the bearing and oil, enough heat to boil all the coolant sitting in the turbo away. Its your engine, do what you want. It will probably survive- but then most turbos have always "survived" too. If you want it to last the longest it possibly can, idle it or get a turbo timer. Most people here are about going the extra mile, not just doing the minimum necessary.
 
The turbo part is a dead issue here. I understand what the guy posting about the heat soak, but seriously, that is not really an issue any more. Turbo timers are just novelty items and are pretty much useless. The turbo housing on most if not all modern turbo charged cars never get hot enough to "Coke" synthetic oil. Most flash points of Synthetics are in the 400+ range and the peices never get that hot when water and oil cooled. Now if you have no oil cooler, and no coolant lines running to the turbo, THEN the idle down would be necessary. Again, No Evo Engine builder that I have heard of (and I know many) NEVER idle down a car unless they were just bouncing off the rev limitier for the past 20 laps. In that case they do. But on the street,you just never will see the temps to justify the idle time. Again, unless you were bouncing off the rv limiter all the way home, get in your garage and just shut it down.

As for the guy with the 1000hp race car, that is frickin sweet, and keep in mind my car on the street is putting out the same HP per liter as your LS2 powered race car. So you understand where I am coming from as per say the oil questions.

I am on the fence with the whole oil stuff. Seems there is SO much bias on these boards. BUT everyone brings to the plate some knowledge that can help the next guy.
 
Last edited:
Additionally, I just got an email back from Royal Purple when I was inquiring about their 5w30 XPR. Here is what was said:

From me:

Chris,

Thanks for the info bud. You have any product info on the XPR series? cSt's, etc? For my own info these oils like the API oils you sell are all group 4 oils right?

Can you give the zddp content? Or is that hush hush for the 5w30 XPR?

Royal Purples Response:

Hi Jeff,

Unfortunately, I cannot give out specifics on the XPRs. Completely proprietary. I can tell you that the zinc and phosphorus levels of XPRs is generally in excess of 1,300 ppm each and that the viscosity of the oils fall within the SAE specified ranges (see table below).

SAE cSt @ 100C
20 5.6 - 9.29
30 9.3 - 12.49
40 12.5 - 16.29
50 16.3 - 21.89

The base oils are a proprietary blend of synthetic base oils, including Group IV and Group Vs, and the XPR additive package also contains a higher treat rate of our Synerlec additive technology than any of our other engine oils.

Regards,

Chris

Now when he mentions a proprietary blend of 4/5 base stocks its as if he is also implying that there may be "other" synthetic oil in there. WOuld that be Group 3's?

I am not really sure what synerlec is. I know its supposed to strengthen the viscosity when needed, but if people are saying that RP oils "thin" out, then is this stuff working? I know I don't need that much ZDDP in my motor, and for $15 per qt, I am thinking I may just stick with my Mobil 1 10/30EP or possible switch to the Mobil 1 0-40. I just dont think a 40W is needed in my case. But what do I know. haha. The Tuners are saying to use a 20/50 and I argue with them over that pont all the time...so back to square zero haha
 
Yes, I did by email. Dave is always prompt when responding with email. Here is what I asked well the last time with David:

David,

Thank You for your time. I just wanted a couple more momments of your time.

I must admit, 1 reason I am considering your product is that your in California and I like supporting companies in my own state. We all know how much CA needs the help, and its business's.

I am coming from using a mainly PAO based oil (Mobil 1 10/30 EP) that has been used in my car for 42K miles. In my original email to you I told you that I have an upgraded Valvetrain, and running about 5lbs more boost than stock (27psi max spike) and you recommended the Redline 5w30 for me. My question is, will there be any problems with seal swelling going from the PAO based oils, to the Ester based oils of Redline? I just don't want to have any issues down the road from switching. Hope this isn't a ridicolous question to ask. I am learning
smile.gif


Thanks for your time,

Jeff

David's Response:

Jeff,


We appreciate the support Californians need to stick together…


Our oils are designed with comparable seal swell to petroleum oils and then should be similar to a good PAO product. You shouldn’t have any issues with seals when switching over to our oil.


Feel free to send me any questions, not ridiculous at all.


Regards, Dave
Red Line Oil

second response, the 1st one was what oil from Rdline I should use...this was his response:

Jeff,


Thank you for contacting Red Line Oil, in your Evo for your range of use the 5W30 would be recommended a good choice for street use and Solo II performance use.


Regards, Dave
Red Line Oil
 
So, I have narrowed the "try" oils down to these.

1) Redline 5/30

2) GC 0-30

3) RP XPR 5/30

I am currently running Mobil 1 10/30 EP. I like the idea of a 0 weight oil. Better circulation on "cold" starts is a no brainer to me. I like how I can get the GC 0-30 (German Brown) at the local store for about $8.00 p/qt. The Redline runs about $9.00 p/qt, and the RP XPR runs about $13. I would be doing oil analysis down the road, not right this second since I need whatever oil I use to have at least 2 oil changes to get all the old oil out so its not contaminating the test. I may send in a sample next oil change just to check for coolant in the oil since I had my head studs changed to ARP's and want to make sure the head is sealing right. But other than that, the oil breakdown would not be too accurate in chemistry breakdown till the 2 interval change IMO.

I like the Redline is local, fairly easy to get, but still would have to pay for shipping. The RP XPR is a good oil but [censored] %13 p/qt??? and the GC 0-30 I really do feel would be an upgrade to the 10/30 Mobil 1 EP because it does have more ZDDP than the M1 EP 10/30 and the 0 weight should help eliminate some start up wear, even though that would be marginal, but every little bit helps.

I will change the oil every 3-5K miles or 6 months whichever comes first and the oil WILL see dyno time and Solo II time. It will also see the 120F heat here of the desert in the summer too. I don't really want to switch weights if I don't have to, winter/summer. Coldest it gets where I am is in the 30's in the winter, and the car is garaged. So what do you guys think?

Also, I know many "Evo" owners are stereotyped as punk kids with rich parents, but I am a working professional, married, 2 kids, and pushing 40. So I don't fit that mold, haha. I just like the car for its performance capabilites, 4 doors, and its overall potential.

So what do you guys and gals think?
 
Status
Not open for further replies.
Back
Top Bottom