I'd think to determine this, you'd have to have an emission test done with your "current" setup "first" so you can get a base-line....
But it goes without saying, new oil is going to have less emissions than old oil...which is why most people recommend changing the oil, filter, air filter, and optionally, the spark plugs before an emission test...just to kill as many "variables" as possible...that could set off red flags for bad emission results.
That being said, I could understand Diesel Oils being more "emission friendly" being that they tend to be thicker, and more robust, less tendency to burn off....? But I think the latest/greatest "SN" oils are being manufacturered to be more emission/environmentally friendly, per "CAFE" standards.....and you may notice, if you browse the labels on the diesle oils, some still meet API "SM" ratings....due to the different additive requirements that have been changed for the "SN" formulation....