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Going from a non-OAT system to an OAT coolant is a no-no. You can use silicated in an OAT system, but not the other way around. G-05 is the exception that proves the rule. Why someone would want Dexcool in their engine is another issue.
Funny, done all the time on older CAT enines with the switch to EC-1 Coolant (close kin of Dexcool). Only result that I know of was a dramatic drop in water pump failures (trending downward to 90% less after 1 year). I switched one at 122,000 mi and the engine/cooling system is still going strong at 800,000 mi +. This includes the original waterpump.