I have personally used a mixture of Redline MT-90 and MTL in my former VW 02J 5-speed manual with decent results. After a few hundred thousand miles I noticed that the fluid would turn black rather quickly and this concerned me. I was not able to determine what was causing the discoloration but the transmission lasted 221,000 miles before the car was totalled. Never any synchronizer issues and was on the original LUK clutch. Shifting characteristics were good.
Fast forward to today and I will be using the OEM VW transmission oil in my 6-speed manual Jetta. The VW part number is G070 726 A2 and sells for about $12,50 per liter.
The older 02J 5-speed in the 1.8T Jetta specified G 50 fluid, part number G 005 000. This is a rather old fluid and has been used in VW transmissions for ages. The 02J can be very picky about viscosity and therefore I strongly recommend AGAINST buying 75W-90 gear oils that are designed for rear axles. They will cause notchy shifting and practically make shifting impossible in cold temperatures.
I know it goes against the DIY psyche but I'd go to the dealer and get 3 liters of G50 and get on a 100,000 mile interval.