Grok had to scratch its head on that one:
Here’s a concise comparison of the lubricating properties of engine oil (circa 1950), coal tar, wood tar, and tree sap, focusing on liquefaction temperatures and lubricating abilities at typical engine block temperatures (around 200–250°F or 93–121°C).
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### Engine Oil (Circa 1950)
- **Liquefaction Temperature**: Already liquid at room temperature (derived from crude oil via fractional distillation, processed to remain fluid above -20°F/-29°C).
- **Lubricating Ability at Engine Temps**: Excellent. Mineral-based oils (e.g., SAE 30) with viscosities optimized for 200–250°F provided strong boundary lubrication, reducing friction and wear (friction coefficient ~0.1–0.15). Additives like ZDDP were emerging by the 1950s to enhance performance.
- **Notes**: Designed for engines, stable at operating temps, though prone to breakdown above 300°F (149°C).
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### Coal Tar
- **Liquefaction Temperature**: Becomes workable around 176–212°F (80–100°C), fully liquefies above 392°F (200°C) depending on composition (high in aromatics).
- **Lubricating Ability at Engine Temps**: Poor. Viscous and sticky at 200–250°F, it lacks fluidity for effective lubrication (friction coefficient ~0.3–0.5). Better suited as a sealant or precursor for synthetic lubricants (e.g., via coal liquefaction processes like Fischer-Tropsch).
- **Notes**: Not practical for engines; decomposes and leaves residue at higher temps.
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### Wood Tar (e.g., Pine Tar)
- **Liquefaction Temperature**: Softens at 122–158°F (50–70°C), liquefies around 212–302°F (100–150°C) via destructive distillation.
- **Lubricating Ability at Engine Temps**: Moderate to poor. At 200–250°F, it’s viscous and sticky (friction coefficient ~0.2–0.4), offering some lubrication for low-speed, heavy-duty applications (e.g., wooden bearings), but it degrades and gums up under sustained heat.
- **Notes**: Historically used as a crude lubricant, but unstable and inefficient in engines.
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### Tree Sap (e.g., Resin-Based)
- **Liquefaction Temperature**: Varies widely; softens at 86–140°F (30–60°C), liquefies around 212–392°F (100–200°C) depending on water content and species (e.g., pine sap).
- **Lubricating Ability at Engine Temps**: Very poor. At 200–250°F, it’s either too thick or evaporates, leaving resinous deposits (friction coefficient >0.5). Lignum vitae wood, saturated with sap, self-lubricates in low-temp, wet conditions, but not in engines.
- **Notes**: Natural viscosity unfit for high-speed machinery; burns or hardens under heat.
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### Summary
- **Engine Oil (1950)**: Best lubricant at engine temps—low friction, stable, purpose-built.
- **Coal Tar**: Too viscous, poor flow, impractical for engines.
- **Wood Tar**: Marginal lubrication, degrades quickly in heat.
- **Tree Sap**: Ineffective, sticky, and thermally unstable.
Engine oil far outperforms the others due to its tailored viscosity and thermal stability at 200–250°F. Tars and sap lack the fluidity and durability needed for engine blocks.