With a cold engine chances are both the 5W and 10w have pretty much drained back to the pan, when using the same brand/quality oil. I still believe the 5W will still get to the parts faster and easier than the 10W upon cold starting. If your engine calls for 10W-30 I'm not saying use 5W-30. But if your engine calls for 5W-30, especially if it's an OHC engine, you're probably best off sticking with the 5W-30.
Whimsey