It may have been covered here already, but I'll hit a few high points again.
Typically, the "grease" that is included with new spark plug wire sets is of the silicone variety. It is very commonly used in many different fields of high voltage work(my occupation, BTW). Keep in mind that silicone lubes are not detrimental to products that contain natural rubber which I believe is present in some plug wire boots. ( natural rubber and rubber compounds of some types are of course very good electrical insulators) In this instance, the small pack of silicone grease included with new plug wires is meant to be used sparingly on the inside of the plug boot and SHOULD NOT be allowed to come into contact with the top of the spark plug itself, or the connector area of the plug wire that is innermost in the boot. Allowing that to happen is about the same as wrapping the top of the spark plug with a thin layer of insulating tape and then making the connection. Silicone grease is a very good insulator.
On the other side of the coin, the "grease" or compound found inside of many automotive connections is made to be used right on the connection. It is moisture and oxygen inhibiting and is also somewhat conductive. However, you'll not find it used where natural rubber insulation is employed because this "grease" is petroleum based in most instances and will attack rubber insulation.
So remember, petro based products should definately NOT be used where rubber or rubber based insulation is used.
Silicone is an electrical insulator so don't let it get between terminals that are to be connected electrically.
Typically, the "grease" that is included with new spark plug wire sets is of the silicone variety. It is very commonly used in many different fields of high voltage work(my occupation, BTW). Keep in mind that silicone lubes are not detrimental to products that contain natural rubber which I believe is present in some plug wire boots. ( natural rubber and rubber compounds of some types are of course very good electrical insulators) In this instance, the small pack of silicone grease included with new plug wires is meant to be used sparingly on the inside of the plug boot and SHOULD NOT be allowed to come into contact with the top of the spark plug itself, or the connector area of the plug wire that is innermost in the boot. Allowing that to happen is about the same as wrapping the top of the spark plug with a thin layer of insulating tape and then making the connection. Silicone grease is a very good insulator.
On the other side of the coin, the "grease" or compound found inside of many automotive connections is made to be used right on the connection. It is moisture and oxygen inhibiting and is also somewhat conductive. However, you'll not find it used where natural rubber insulation is employed because this "grease" is petroleum based in most instances and will attack rubber insulation.
So remember, petro based products should definately NOT be used where rubber or rubber based insulation is used.
Silicone is an electrical insulator so don't let it get between terminals that are to be connected electrically.