Chris142.....Nope. there is a rule of physics called the conservation of mass.
Supton: Nah. The piston acts like a pump.....it will pull any air in that it needs. If it can't, you'll see your air filter or intake collapse. Any and all ambient atmospheric pressure is irrelevant.
Just a theory, I have no why to prove it...but I think the exhaust valve is bigger because exhaust gases are MUCH hotter than the intake charge. As the temperature rises, so does volume. So there is actually a larger volume of gas that needs to exit than what entered. Hence, the larger exhaust port.
I never imagined a answer could be more than 100% wrong...
Atmospheric pressure fills the cylinder, large valve(and ports) lets air in more easily... Ever consider why a engine looses power at high altitude??? Less pressure...
Exhaust valve(and port) smaller, the fast rising piston and expanding exhaust gasses create far more pressure than will ever seen on the intake, even if engine is boosted...