you have a hypothesis, but no actual science to back it up.
Well the NOACK volatility test is predictive of how much an oil will vapourize when actually placed in service in an engine. Where do you suppose the components of motor oil that are 'lost' when oil is placed into service end up? Into the PCV system, and ultimately, deposited onto those exhaust valves.
You claim that if the oil were left it that the deposition rate would decrease. What do you base this on? Thus far NOACK volatility. However, NOACK volatility is measured on new, uncontaminated oil, not oil that has been fuel, ethanol and water diluted and degraded.
A chemical reaction, per se, does not occur between molecules of motor oil, and molecules of contaminants in such motor oil. If you dissolve one quart gasoline in one quart motor oil, you can, through the process of distillation, seperate the two components into their original constituents, ie: you're left with one quart gasoline, and one quart motor oil. The only exception to this is when you have combustion of the actual components, but this does not occur at the pressures and temperatures present in the crankcase.
As for water, and ethanol, these substances don't exist in motor oil, at engine operating temperatures, long enough to cause any harm (such as emulsification).
So what you're left with, in PCV vapour, is a mixture of blowby gases, and volatilized motor oil. Blowby gases, by definition, are gaseous combustion byproducts that don't cause much of any deposition (just look at the exhaust on a modern car -- there's extraordinarily little in terms of particulate matter deposited on exhaust components these days!). So what are you left with? Volatilized motor oil.
We know that new motor oil is much more volatile than motor oil that has been in service. So much of the solution revolves around ensuring that the oil that is in service has the lowest volatility possible. Its no coincidence that a major part of the modern API oil specs, and a real driver towards the use of synthetic and semi-synthetic oils in manufacturers recommendations have been driven by volatility concerns.
If one keeps changing their oil every few thousand miles, this is just ensuring that the oil that's in their crankcase is as volatile as it possibly can be, creating exactly the problems as described in this thread.
As a matter of fact, some of the RS4 engines in the UK that have had severe valve deposit issues had their oil changed per the manufacturers recommendation, with manufacturer recommend oil.
Maybe the manufacturer's recommendations are overly aggressive on oil changes. As we've discussed here
extensively recommended OCI's are often not based on good science, but are rather, based on marketing or non-scientific criteria, good or bad.