Yes the Esters are key to the cleaning aspect of a motor oil, But... if the chemistry is busy being worked to clean you will sacrifice lubricity. In every vehicle I tested the Auto-RX formulation in, syn and non syn oils the oxidation rose during cleaning, nitration dropped during and after treatment, whether the operator could see a difference in the oil color or cleanliness of filters/components etc. Also emissions tests backed this observation up.
That tells me from and analysis point of view that this stuff cleans where normal solvents miss the mark, the rings, valveguides, etc.
My understanding of the esters in Auto-RX is that they are derived are from a natural source. It includes other natural sourced esters that provide lubricity, EP, and some pourpoint help since it gets thick quick in cooler weather.
I do know that the primary esters for cleaning are not found in ANY other automotive application in the world. To be gentle to metal and clean hardened carbon is really amazing to me.
I'm one of the guys a few years ago who would have agree that Amsoil or Redline was the way to keep clean, and was a NO adds kind of guy. Since I have No allegience to any brand including Auto-RX I tell it like I see it tested. So as time moves on and we test more I see things change.
Sorry for the ramble.