let's say the engine is hot on shutdown. The oil's viscosity will be thin, so if it didn't have any surfactants, it would drip off, no matter what the original viscosity.
Most modern oils, whether dino or synthetic, have a small amount of clinging surfactant to maintain a bulk oil presence after engine shutdown. Now at the thin film or molecular level, an oil with esters will provde more wetting over the surface, since the clinging is done at the molecular level, and not the "bulk" level.
I think one needs to examine the differences between bulk oil (macroscopic view) verses thin films at the molecular level (microscopic view).
Most cars and trucks need FM and AW adds to be deposited in the heads. It is the additives that protect on startup until the oil flow is established.