Let's back up a bit...
Tap water, drinking water, has lots of dissolved salts in it. Salts in chemistry, by the way, aren't just sodium chloride, but a combination of a positive ions and negative ions. When dissolved in water, they can make an acid, a base, or be neutral. So, the salts in your water are a combination, calcium is common, but sodium and others are in drinking/tap water, really depends on the source, but water leaches those elements from the rock or aquifer from which its extracted.
Bottled water marketers, like Dasani, even add calcium carbonate, magnesium sulfate, and potassium bicarbonate for taste. They add salts, in other words.
If you have "hard" water in your town, or well, there are lots of dissolved salts. That's what causes build up of crust on your shower head or leaves "water spots" on your car when you wash it. The salts that are left when the water evaporates.
Pure water is just that: water with nothing else in it.
De-ionized water is regular water with ions removed. Pretty close to pure.
Distilled water is pure, nothing else was evaporated and distilled back in, so, pure.
De-ionized water and distilled water are used in labs to clean so that no salt residue is present after rinsing and drying lab equipment. It doesn't "clean" - that is remove dirt and soap - any better than regular water, but the point is after rinsing and drying, there will be no residue left on the equipment.
So, that's the background.
On to the claims that are made:
1. Mercedes specified not to use distilled. I hadn't heard this, and it's not in my service information for my Mercedes, which still recommends the use of distilled.
Got a source for that?
2. The reason for Mercedes change is the "hungry for ions" nature of distilled water "leaching ions" from the metal. OK, let's go back to 1. above. IF Mercedes changed their recommendation, when did they give this reason?
Got a source for that?
I can find lots of sites on the web making ridiculous claims, e.g. the Earth is flat, so, finding sites that claim something is hardly proof.
Before anyone can answer "what chemistry is behind this recommendation", I really want to validate that the recommendation is, in fact, true.
Because, in reading the posts you're making
@willbur, it all looks like internet hearsay.
When you read Mercedes' specification for cooling systems, there is a MAXIMUM number of dissolved salts of various kinds. There is NO minimum amount of dissolved salts. The best way to get under that maximum, without extensive testing of your tap water? Use distilled or deionized water. Since there is NO minimum amount of dissolved salts recommended, a water with zero salts, like distilled, meets Mercedes' current specification.
Die Mercedes-Benz Betriebsstoff-Vorschriften zeigen eine Übersicht der Anforderungen der im Fahrzeug benötigten Betriebsstoffe und der empfohlenen Produkte. Betriebsstoffe sind alle zum Betrieb eines Mercedes-Fahrzeugs / Aggregats erforderlichen Flüssigkeiten bzw. Schmiermittel z.B. Kraftstoff...
bevo.mercedes-benz.com