Several points I want to make quickly.
I agree with Leo's statement about clinging. Oil, like many other liquids are held together by ionic tension. Viscosity of the oil will determine the amount of time the oil will "cling" than the "magnetic attraction" some people feel the esters have. Gravity will over come this so called attraction over time. Take the petroleum base stock of lucas's additive, it's not synth but it will cling extremly over any motor oil. It's base stock is much thicker. All motor oils are designed to flow. To say a synth will cling is incorrect.
The only clinging that is happening is where the aw/ep's have been bonded due to the heat/friction to the surface. Point here is, I can take a motor oil, stick it on the timken race, rotate it, then pull it out, and see if it has any protection. No, it will lock right up. Take that same motor oil, run it, create some heat/friction with the two surfaces, and the barrier additives will plate up. drain it, clean it off, and restart with no oil, and it will provide momentary protection. This is due to the barrier additives.
I do not agree that start up wear being that much. When is the highest wear. When an engine is completley warmed up driving in traffic. What most are forgetting is LOAD. At a start up, cold or warm, you have no load on the engine until you put it in gear to move. Starting an engine has no load thus do demand to shear the oil film.
At stop and go traffic, the wedge of oil is minimal and as someone commented, it's when you have a heavy foot from light to light that's when you create wear. The amount of scuffing due to load/shear of the wedge oil is dramitic.
You'll see many "little old lady's" drive their car local, start it, put it in gear, do the in town driving only and it never wears out, but take same car,with the same amount of startups, put a young person, they do jackrabbit starts from each light, and see the difference. The little old lady does easy starts off at lights, the other, putting heavy load and demand on the engine at start while the wedge between the parts is a mixed film at best.
So, imo, stop and go traffic with a heavy foot is where most wear is created, not startup.