I will let you in on a little know secret with the RAM 6.4. All developmental test by FCA for that engine variant used a conventional 5W-30.
When that engine debuted in late 2013 for the 2014 RAM HD models, both the head of the RAM division and the Chief Engineer for RAM had an informal online video chat session that was posted on RAM Truck Youtube channel not shortly after discussing the new refreshed RAM HD models and taking questions. One of the questions asked to them specifically was if the 0W-40 and MS-12633 oil required? Out of their mouths was a “no” and the statement that all testing was done on the RAM 6.4 engine with conventional 5W-30. That video was on their Youtube Channel for over year and mysteriously disappeared.
That being said and like any owners manual recommendations, you have to weigh to personal risks of not following it. The path of least resistance is to follow the owners manual. I had a 2015 RAM 2500 6.4 and ran the Pennzoil Platinum 0W-40 for 4 oil changes. My last and final oil change before I traded it off, I ran MAG 1 Full Synthetic 5W-30 with an oil analysis from Blackstone that came back showing no negative wear for using.
You will probably be fine using Mobil 1 or any other manufacturer 0W-40 API SN rated product but you will assume that risk if in the rare event an oil related failure occurs or other mechanical issue arise and the questions of what oil you used comes into play. Internet lawyers will tell you that FCA will have to prove your use of a non recommended or Spec’d oil caused the failure, but they will not be standing next to you with financial help if you have to legally fight that battle.
I will say that with quite a few instances of failed Hemi engines for both the 5.7 and 6.4, a common denominator data point was the oil used had levels of molybdenum in their formulas. That is one ingredient in the Pennzoil 0w-40 that stands out is a higher than average molybdenum level.