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Got a website, and do you ship? Millipore Sigma charges $180 a gallon.

Found this article which explains/supports your empirical observation regarding odor:

I joined BITOG largely to say thanks to you for the convenient table of CAS numbers for different mineral spirit types ;) I am quite seriously looking for substitutes for Stoddard solvent in my application, since the number of places selling it has gone down substantially and the price has...

This post is a nice summation of the information that is out there. I'm not a real chemist but a lot of these things would be defined by what cuts were taken during distillation. If the cuts overlap (which they do) the chemical compositions will be similar but not identical. Characteristics...